Synthesis of volicitin: a novel three-component Wittig approach to chiral 17-hydroxylinolenic acid
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 12,p. 1087-1088
- https://doi.org/10.1039/a902020i
Abstract
A short stereoselective synthesis of both enantiomers of N-(17-hydroxylinolenoyl)-L-glutamine (volicitin) 12, an elicitor of plant volatile biosynthesis from beet armyworm salivary secretion, is described; the protected 17-hydroxylinolenic acid 4 moiety of volicitin 12 was prepared in a one pot bis-Wittig reaction.Keywords
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