Hypervalent iodine oxidation of α,β-unsaturated ketones: chromone, flavone, chalcone, and flavanone
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 927-929
- https://doi.org/10.1039/c39840000927
Abstract
Reaction of the title compounds with PhI(OAc)2 and MeOH–KOH leads to α-hydroxydiemthylacetal β-methoxy products regiospecifically and stereospecifically, as demonstrated by X-ray diffraction.Keywords
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