Chemistry of Proximal π-Bond Systems. Part I. Synthesis of Vicinal Exocyclic Dimethylene Hydrocarbons
- 15 March 1972
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 50 (6) , 795-802
- https://doi.org/10.1139/v72-124
Abstract
Thirteen new bi- or polycyclic vicinal exocyclic dimethylene hydrocarbons (10–22) have been synthesized and some of their spectral properties recorded. The generally most useful synthetic route to such compounds utilizes base-catalyzed double elimination from trans-1,2-bis(hydroxymethyl)alkyl p-toluenesulfonates as the final step in the production of the conjugated diene.Keywords
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