Non-coplanar symmetric (e, 2e) momentum profile measurements for helium: an accurate test of helium wavefunctions
- 14 June 1984
- journal article
- Published by IOP Publishing in Journal of Physics B: Atomic and Molecular Physics
- Vol. 17 (11) , 2339-2352
- https://doi.org/10.1088/0022-3700/17/11/025
Abstract
The 1200 eV non-coplanar symmetric (e, 2e) cross sections for helium leading to the n=1, 2 and 3 ion states were measured with a modified coincidence spectrometer using position-sensitive microchannel plate detectors. The ground-state momentum profiles (cross sections) are compared with the momentum distribution given by the Hartree-Fock wavefunction, the accurate correlated wavefunction of Joachain and Vanderpoorten (1970), and the momentum distribution derived from accurate Compton profile measurements by Lee (1977). Good agreement is obtained between theory and the (e, 2e) measurements, but the Compton momentum distribution is seriously in error at low momentum. The small discrepancy at high momenta between the present measurements and the plane-wave impulse approximation is completely explained by allowing for distortion of the continuum electron waves by the helium and ion potentials. The n=2 and 3 cross sections cannot be explained using the helium HF wavefunctions, but are well described by the accurate correlated JV wavefunction. The measured n=2 to n=1 cross section ratio discriminates between several accurate correlated helium ground-state wavefunctions.Keywords
This publication has 26 references indexed in Scilit:
- Electron momentum distributions and binding energies for the valence orbitals of hydrogen bromide and hydrogen iodideJournal of Electron Spectroscopy and Related Phenomena, 1982
- Binary (e, 2e) spectroscopy and momentum-space chemistry of CO2Chemical Physics, 1982
- Momentum distributions and ionization potentials for the valence orbitals of hydrogen fluoride and hydrogen chlorideJournal of Electron Spectroscopy and Related Phenomena, 1980
- A critical evaluation of high energy electron impact spectroscopy to measure Compton profilesJournal of Physics B: Atomic and Molecular Physics, 1978
- Excitation of the n=2 states of He+in the ionization of heliumJournal of Physics B: Atomic and Molecular Physics, 1976
- Roothaan-Hartree-Fock atomic wavefunctionsAtomic Data and Nuclear Data Tables, 1974
- Quantum mechanical first Born binary encounter theory of electron impact ionization. II Electron Compton scatteringThe Journal of Chemical Physics, 1973
- Gamma-Ray Compton Scattering: Experimental Compton Profiles for He,, Ar, and KrPhysical Review A, 1972
- Electron Momentum Density of He and; Compton X-Ray ScatteringPhysical Review A, 1970
- A Direct Spectrum of the Structure and Shift of the Compton Line with Helium Gas as the ScattererPhysical Review B, 1937