The Stereochemistry of Tritium Substitution by the Wilzbach Method. I. ( - )-Inositol
- 1 January 1963
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 16 (2) , 252-257
- https://doi.org/10.1071/ch9630252
Abstract
The stereochemistry of tritiation of crystalline (-)-inositol and its liquid hexa-O-methyl derivative by the Wilzbach labelling procedure has been investigated. Predominance of configurational retention was found to accompany substitution in the crystalline compound, whereas configurational inversion predominated during substitution in the liquid.Keywords
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