Multiple methylene insertion reactions: the crystal structure of a complex formed by insertion of methylene into a Pt–P bond
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 614-616
- https://doi.org/10.1039/c39820000614
Abstract
Up to three methylene groups from diazomethane may be incorporated into hydridodiplatinum(I) complexes by insertion into Pt–Pt. Pt–H and, in one case, a Pt–P bond; X-ray structure determination establishes the an M2(µ-CH2) group with no M–M bond are reported.Keywords
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