Synthesis and copolymerization behavior of methacrylate dimers
- 1 December 1993
- journal article
- research article
- Published by Wiley in Journal of Polymer Science Part A: Polymer Chemistry
- Vol. 31 (13) , 3417-3424
- https://doi.org/10.1002/pola.1993.080311330
Abstract
Methacrylic ester‐based dimers and oligomers were synthesized using a metal‐based catalytic chain transfer agent. Conditions were employed which maximized the yield of unsaturated dimers, and the copolymerization behavior of these dimers was investigated. The molecular weight and polymer yield were found to decrease with increasing dimer concentration in the copolymerization feeds. © 1993 John Wiley & Sons, Inc.Keywords
This publication has 10 references indexed in Scilit:
- Polymerization reactivity of unsaturated end group generated during the disproportionation in termination reaction of methyl methacrylate polymerization: A study using model compoundsJournal of Polymer Science Part A: Polymer Chemistry, 1989
- Determination of reactivity ratios in copolymerizationMakromolekulare Chemie. Macromolecular Symposia, 1987
- Structures and compositions of copolymersMakromolekulare Chemie. Macromolecular Symposia, 1987
- Cobaloxime as a catalytic chain transfer agentJournal of Polymer Science: Polymer Chemistry Edition, 1984
- Kinetics of radiation postpolymerization of butyl acrylate in the presence of cobalt porphyrinRussian Chemical Bulletin, 1984
- Thermal and photochemical polymerization of methyl methacrylate in the presence of cholesteric liquid crystals and tetraphenyl porphyrinsPolymer Photochemistry, 1984
- Kinetic study of catalysis of the chain transfer reaction to monomer in the radical polymerization of methyl methacrylatePolymer Science U.S.S.R., 1981
- Catalyzed chain transfer to monomer in free radical polymerizationJournal of Polymer Science: Polymer Chemistry Edition, 1981
- Comparison of the precision of estimation of copolymerization reactivity ratios by current methodsJournal of Polymer Science: Polymer Chemistry Edition, 1980
- Comonomer and stereosequence distributions in high polymersJournal of Polymer Science Part A-2: Polymer Physics, 1970