Sodium Iodide-Chlorotrimethylsilane (Or Boron Trifluo-ride Etherate) and Zinc-Chlorotrimethylsilane: Mild Reagent Systems for the Conversion of Enediones Into 1,4–Diketones
- 1 February 1987
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 17 (2) , 181-187
- https://doi.org/10.1080/00397918708057219
Abstract
A high yielding conversion of enediones into 1,4-diketones has been found to proceed under mild conditions by using sodium iodide-chlorotrimethylsilane (or boron trifluoride etherate) and zinc-chlorotrimethyl-silane as reagent systems.Keywords
This publication has 10 references indexed in Scilit:
- Sodium iodide/boron trifluoride etherate: A mild reagent system for the conversion of allylic and benzylic alcohols into corresponding iodides and sulfoxides into sulfidesTetrahedron Letters, 1985
- 2Inc/Chlorotrimethns Ilane: A Mild Reducing System for the Conversion of Epoxides into AlcoholsSynthetic Communications, 1983
- Advances in Cyclopentenone Synthesis from FuransHETEROCYCLES, 1982
- Synthetic methods and reactions. 85. Reduction of .alpha.-halo ketones with sodium iodide/chlorotrimethylsilaneThe Journal of Organic Chemistry, 1980
- Oxidative ring opening of furan derivatives to α,β-unsaturated γ-dicarbonyl compounds, useful intermediates for 3-oxocyclopentenes synthesisTetrahedron, 1980
- A NEW REAGENT, Zn–ZnCl2-ROH, FOR THE HYDROGENATION OF CONJUGATED DOUBLE BONDChemistry Letters, 1976
- Reduction of enedicarbonyl compounds with titanous ionThe Journal of Organic Chemistry, 1974
- Methods for the Synthesis of 3-OxocyclopentenesSynthesis, 1973
- The Reduction of Multiple Bonds by Low-Valent Transition Metal Ions. The Homogeneous Reduction of Olefins by Chromous SulfateJournal of the American Chemical Society, 1966
- Studies in the synthesis of cortisone. Part IV. The oxidation of steroid 7 : 9-dienes with sodium dichromate in acetic acidJournal of the Chemical Society, 1954