Photo-oxygenation of diphenyldiazomethane in the presence of phenyl trimethylsilyl ketone. Oxygen transfer from carbonyl oxide to the silyl ketone
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 233-234
- https://doi.org/10.1039/c39790000233
Abstract
Dye-sensitized photo-oxygenation of diphenyldiazomethane in the presence of phenyl trimethylsilyl ketone produced trimethylsilyl benzoate by reaction of a carbonyl oxide with the silyl ketone accompanied by 1,2-rearrangement of the trimethylsilyl group, together with benzophenone.Keywords
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