Anomalous temperature effect in electric field orientation of poly(cyclohexylmethylsilane)

Abstract
We observed an anomalous temperature effect for poly(cyclohexylmethylsilane) (PHMS) in a systematic study on formation of electrically oriented polysilane films by casting on interdigital electrodes to which a dc voltage is applied. The orientation of PHMS is quite sensitive to the process temperature: polysilanes align well along the electric field at 14 °C but do not at temperatures higher than 15 °C or lower than 11 °C. It is also shown that the degree of orientation of polysilanes in the films reflects to the electric conduction.

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