IONIZATION OF ORGANIC COMPOUNDS: V. THIOLACTAMS IN SULPHURIC ACID
- 1 March 1963
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 41 (3) , 721-725
- https://doi.org/10.1139/v63-102
Abstract
The ionization in aqueous sulphuric acid of thiolactams consisting of five-, six-, and seven-membered rings has been studied. With increasing concentration of acid the ionization ratio increases more rapidly than h0. A possible explanation involving the hydration of the thio-lactam is given. Changes in the basicity of thiolactams with ring size parallel changes previously found for lactams.Keywords
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