Kinetic determination of the bond dissociation energy D(Me₃SiCMe₂CH₂–H) and the magnitude of the stabilisation energy in a β-silicon-substituted alkyl radical

Abstract

A kinetic study of the gas-phase reaction between iodine and Me₃SiCMe₃ is interpreted to provide a β-silicon stabilisation energy of ca. 12 kJ mol^–1 in the Me₃SiCMe₂CH₂· radical.

Keywords

KINETICS

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Kinetic determination of the bond dissociation energy D(Me3SiCMe2CH2–H) and the magnitude of the stabilisation energy in a β-silicon-substituted alkyl radical

Abstract

Keywords

Kinetic determination of the bond dissociation energy D(Me₃SiCMe₂CH₂–H) and the magnitude of the stabilisation energy in a β-silicon-substituted alkyl radical