Abstract
Measurements on the polarization of resonance radiation in a magnetic field have been used to obtain the hyperfine separation constants of the 6P322 and 7P322 levels of caesium I. For a nuclear spin of 72 the hyperfine separation constant is 1.42×103 cm1 for the 6P322 level and 4.86×104 cm1 for the 7P322 level. From these values the nuclear magnetic moment is calculated as 2.401840 and 2.411840 Bohr magnetons, respectively. These agree well with the value 2.521840 obtained from the splitting of the lower 6S122 level. The theoretical and experimental curves for the polarization as a function of the magnetic field agree within experimental error when the shape of the exciting line in the source is taken into account.

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