A Water‐Complexed Organolithium Compound: [LiCH(CN)2 · H2O · TMEDA]∞
- 1 January 1992
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 31 (1) , 77-79
- https://doi.org/10.1002/anie.199200771
Abstract
Not the bidentate amine ligand, but water coordinates to the Li cation in [LiCH(CN)2 · H2O · TMEDA]∞ 1 (TMEDA = tetramethylethylenediamine), a very unusual structural characteristic for lithiated organic compounds. Inter‐molecular hydrogen bonds between the H atoms of the aqua ligands and the N atoms of TMEDA are observed. 1 is therefore the first water‐complexed lithiated organic compound derived from a CH acid.This publication has 25 references indexed in Scilit:
- The first lithiated organic compound containing water as a ligand: synthesis and crystal structure of 2-mercaptobenzoxazolyl(tetramethylethylenediamine)lithium monohydrate, C6H4OC(S)NLi(tmeda)H2O, a model acid–base intermediateJournal of the Chemical Society, Chemical Communications, 1990
- Röntgenstrukturanalyse von α‐Lithiophenylacetonitril · Lithiumdiisopropylamid · 2 Tetramethyl‐ethylendiamin – ein „Quasi‐Dianion‐Komplex”︁Angewandte Chemie, 1989
- [{Li2(Me3SiCCN)}12(Et2O)6(C6H14)], Kristallstruktur mit dem Trimethylsilylacetonitril‐DianionEuropean Journal of Inorganic Chemistry, 1989
- (Hexamethylphosphorsäuretriamid)lithiumdicyanmethanid, [LiCH(CH)2(hmpt)]n, eine polymere Verbindung mit dem Malonodinitril‐AnionEuropean Journal of Inorganic Chemistry, 1988
- Kristallstruktur von [α-Nitrobenzyllithium · Ethanol]n; eine Lithiumnitronat-Ethanol-WechselwirkungAngewandte Chemie, 1987
- Crystal Structure of [α‐Nitrobenzyllithium · Ethanol]n; A Lithium Nitronate‐Ethanol InteractionAngewandte Chemie International Edition in English, 1987
- [(a‐Cyanbenzyllithium·Tetramethylethylendiamin)2·Benzol]: Röntgen‐Strukturanalyse eines α‐Nitril‐„Carbanions”︁Angewandte Chemie, 1986
- [(α‐Cyanobenzyllithium. Tetramethylethylenediamine)2. Benzene]: X‐ray Structure Analysis of an α‐Nitrile “Carbanion”Angewandte Chemie International Edition in English, 1986
- Refinement of pyroelectric lithium perchlorate trihydrateActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1977
- Refinement of the crystal structure of lithium hydroxide monohydrateActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1971