Activation of linear and cyclic saturated hydrocarbons involving arene–rhenium compounds: crystal structure of µ-dihydrido-µ-neopentylidene-bis(η-benzene)-dirhenium
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 240-242
- https://doi.org/10.1039/c39840000240
Abstract
Co-condensation of rhenium atoms with a mixture of benzene and an alkane, RH = ethane, propane, butane, 2-methylpropane, neopentane, tetramethylsilane, cyclopentane, or cyclohexane gives the compounds [(η-C6H6)Re(η-H)2(η-CR′R″)Re(η-C6H6)], where CR′R″= CHMe, CHEt and CMe2, CHPrn and CMeEt, CH(CHMe2), CHBut, CHSiMe3, cyclopentylidene, or cyclohexdylidene respectively: the crystal structure of the compound where CR′R″= CHBut has been determined.Keywords
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