The primary photoproducts of Mn2(CO)10: direct i.r. observation and decay kinetics of Mn(CO)5 and Mn2(CO)9 in hydrocarbon solution at room temperature
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 785-786
- https://doi.org/10.1039/c39840000785
Abstract
Time-resolved i.r. spectroscopy is used to show that Mn(CO)5 and CO-bridged Mn2(CO)9 are the primary photoproducts of Mn2(CO)10 in hydrocarbon silution; 2Mn(CO)5→ Mn2(CO)10 and Mn2(CO)9+ CO → Mn2(CO)10 are established as the recombination processes.Keywords
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