“Inverse-Electron-Demand” Ligand Substitution in Palladium(0)−Olefin Complexes
- 5 December 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (1) , 12-13
- https://doi.org/10.1021/ja028738z
Abstract
Ligand substitution reactions are ubiquitous in transition-metal chemistry and catalysis. Investigation of ligand substitution reactions for a series of electron-rich palladium(0)−olefin complexes, (bathocuproine)Pd(nitrostyrene) reveals an unprecedented mechanism in which the metal serves as the nucleophilic partner in an “associative” substitution pathway.Keywords
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