Reduction potentials for µ-superoxo/µ-peroxo-dicobalt(III) couples
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 8,p. 1621-1624
- https://doi.org/10.1039/dt9820001621
Abstract
Reduction potentials (versus n.h.e.) determined by cyclic voltammetry are reported for 11 µ-superoxo/µ-peroxo-dicobalt(III) couples. A dependence of E values on the identity of bridging and terminal ligands, and on the degree of chelation of amines is observed. The effect of protonation of µ-peroxo ligands on E values at pH < 3 is noted.Keywords
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