Mixed Ligand Derivatives of 1: 1 Th(IV)—DTPA Chelate with Some Hydroxy Acids(H)
Open Access
- 1 October 1975
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 30 (9-10) , 751-754
- https://doi.org/10.1515/znb-1975-9-1017
Abstract
Studies of the interaction between 1:1 Th(IV)-DTPA chelate (where DTPA = diethylenetriaminepentaacetic acid) with certain bidentate ligands, such as salicylic acid (SA), 5-sulphosalicylic acid (SSA) and 8-hydroxy quinoline-5-sulphonic acid (HQSA) have been carried out potentiometrically. The nature of the titration curves indicates that the bidentate ligand is added stepwise to the initially formed metal diethylenetriaminepentaacetate. The formation constants (log KMAB) of the resulting 1:1:1 mixed ligand derivatives have been determined at 30 ± 1 °C and μ = 0.1 (KNO3). The order of stability in terms of the secondary ligand has been found to be SA > SSA > HQSA.Keywords
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