Hyperbranched Polymers:
- 1 August 1997
- journal article
- review article
- Published by Taylor & Francis in Journal of Macromolecular Science, Part C: Polymer Reviews
- Vol. 37 (3) , 555-579
- https://doi.org/10.1080/15321799708018375
Abstract
Macromolecular architecture is receiving increasing interest as the search for new tailor-made polymeric materials with strictly specified properties intensifies. Many research groups are now focusing their interest on dendritic macromolecules [dendron (Greek) = treelike, highly branched] i.e. dendrimers and hyperbranched polymers based on ABx-monomers. The high degree of branching for dendritic polymers has some consequences, e.g., no crystallization and no interchain entangling have been observed [1]. This gives rise to poor mechanical properties but good solubility and decreased melt viscosity [2] for dendritic macromolecules as compared to their linear analogs of the same molar mass.Keywords
This publication has 55 references indexed in Scilit:
- Analysis of aromatic polyether dendrimers and dendrimer-linear block copolymers by matrix-assisted laser desorption ionization mass spectrometryPolymer Bulletin, 1995
- Dendritic polymers: from aesthetic macromolecules to commercially interesting materialsActa Polymerica, 1995
- Molecular Ball Bearings: The Unusual Melt Viscosity Behavior of Dendritic MacromoleculesJournal of the American Chemical Society, 1995
- Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Characterization of Poly(butyl methacrylate) Synthesized by Group-Transfer PolymerizationMacromolecules, 1995
- Functional Polymers and Dendrimers: Reactivity, Molecular Architecture, and Interfacial EnergyScience, 1994
- Characterisation of aromatic polyester dendrimers by matrix-assisted laser desorption ionisation mass spectrometryJournal of the Chemical Society, Chemical Communications, 1994
- Synthesis, characterization, and curing of hyperbranched allyl ether–maleate functional ester resinsJournal of Polymer Science Part A: Polymer Chemistry, 1993
- Water soluble hyperbranched polyphenylene: "a unimolecular micelle?"Journal of the American Chemical Society, 1990
- Starburst Dendrimers: Molecular‐Level Control of Size, Shape, Surface Chemistry, Topology, and Flexibility from Atoms to Macroscopic MatterAngewandte Chemie International Edition in English, 1990
- Molecular Size Distribution in Three Dimensional Polymers. VI. Branched Polymers Containing A—R—Bf-1 Type UnitsJournal of the American Chemical Society, 1952