Readily constructed modular polarization-emission scanning spectrometer
- 1 September 1994
- journal article
- research article
- Published by AIP Publishing in Review of Scientific Instruments
- Vol. 65 (9) , 2785-2791
- https://doi.org/10.1063/1.1144617
Abstract
A modular polarization spectrometry system for the measurement of the degree of polarization (linear or circular) of luminescence intensity is described. It is based on polarization modulation with a photoelastic modulator and two lock‐in amplifiers for signal recovery. Interfaced to the spectrometer is a microcomputer configured with CRT monitor, disk drive, and digital printer to provide system control and to permit digital data storage and data manipulations such as multiple scan averaging and averaged background subtraction. The system described is capable of measuring linearly polarized emission, linearly polarized excitation luminescence, and circularly polarized emission spectra. The modular design also allows the spectrometer to be rapidly and easily modified for the measurement of circular dichroism,magnetic circular dichroism, or magnetic circularly polarized emission. The system performance is demonstrated.Keywords
This publication has 19 references indexed in Scilit:
- Circularly polarized luminescence spectroscopyChemical Reviews, 1977
- Theory of magnetic circularly polarized emissionThe Journal of Chemical Physics, 1977
- The pfeiffer CD activity of dd electronic excitations of (CoIIIS6) and (CrIIIS6) chromophores and of [Co(acac)3]Inorganica Chimica Acta, 1975
- Magnetic Circular DichroismAnnual Review of Physical Chemistry, 1974
- Measurement of optical activity in racemic mixturesJournal of the American Chemical Society, 1969
- Emission of circularly-polarised radiation by optically-active compoundsChemical Physics Letters, 1967
- Magnetic Optical ActivityAnnual Review of Physical Chemistry, 1966
- Polarizations and assignments of transitions: The method of photoselectionJournal of Molecular Spectroscopy, 1961
- Spectroscopic Study of Wurster's Blue and Tetramethyl-p-phenylenediamine with Assignments of Electronic Transitions1Journal of the American Chemical Society, 1955
- Polarisation de la lumière de fluorescence. Vie moyenne des molécules dans l'etat excitéJournal de Physique et le Radium, 1926