1,1,2,2,2,2,3,3,3,3-Decacarbonyl-1-(η-cyclohexa-1,3-diene)-triangulo-triosmium: a novel intermediate in synthetic osmium cluster chemistry
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 14,p. 1328-1330
- https://doi.org/10.1039/dt9770001328
Abstract
Cyclohexadiene reacts with [Os3(CO)10H2] under moderate conditions to give [Os(CO)10(C6H8)]. Some reactions of this compound with alcohols, thiols, amines, halogen and organic acids, ethylenes, and acetylenes have been examined, and it is shown that cyclohexa-1,3-diene is a very good ‘leaving group’ and provides a convenient route to a number of triangulo-Os3 cluster compounds.Keywords
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