Proton-transfer spectroscopy of 3-hydroxyflavone in an isolated-site crystal matrix.
Open Access
- 1 June 1984
- journal article
- research article
- Published by Proceedings of the National Academy of Sciences in Proceedings of the National Academy of Sciences
- Vol. 81 (11) , 3375-3378
- https://doi.org/10.1073/pnas.81.11.3375
Abstract
The isolated-site low-temperature crystal matrix (dilute solutions in heptane and in octane) ( Shpol ' skii matrix) is shown to be operative for the spectroscopic study of 3- hydroxyflavone luminescence. The observed luminescence is demonstrated to be unique proton-transfer fluorescence from the excited tautomer. A separate study at higher concentrations of aggregated molecule luminescence and excitation spectra distinguishes these for 3- hydroxyflavone from isolated-molecule spectra. The application of the Shpol ' skii matrix low-temperature spectroscopy technique is suggested for other large heteroaromatic molecules, such as biomolecules containing polar groups that impart low solubility in nonaqueous solvents.This publication has 0 references indexed in Scilit: