Catalytic asymmetric epoxidation of aliphatic enones using tartrate-derived magnesium alkoxidesElectronic supplementary information (ESI) available: conditions for enantiomeric purity determination for epoxyketones derived by di-tert-butyl tartrate mediated epoxidation. See http://www.rsc.org/suppdata/cc/b1/b109421a/
- 27 November 2001
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 2712-2713
- https://doi.org/10.1039/b109421a
Abstract
Simple aliphatic enones can be converted into the corresponding epoxides in 71–93% ee using tert-butylhydroperoxide in the presence of a catalyst derived from dibutylmagnesium and di-tert-butyl tartrate.Keywords
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