Abstract
New calculations of transition probabilities for all the 3p2 forbidden lines, for alternate ions from S III to Sn XXXVII, are presented and discussed. Radial wavefunctions and energy levels were calculated for the 3p2 and five low interacting configurations, using the HXR self-consistent field method and Slater–Condon theory. Detailed relativistic corrections and configuration mixing effects were included. Wavelengths and A values were computed in intermediate coupling with Z-smoothed semi-empirical coupling transformations. Results for Z ≼ 28 agree well with those of Mendoza & Zeippen who used a very different model, and confirm significant improvements over earlier published A values. There is also good agreement with observed energy separations, which now extend to Z = 42. The present results extend the theoretical data to zinc and beyond to Z = 50, thus better illustrating trends in magnetic dipole and electric quadrupole oscillator strengths with Z.

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