Structure and Dielectric Properties of the Ba(Mg1/3Nb2/3)O3‐La(Mg2/3Nb1/3)O3 System
- 1 August 1998
- journal article
- Published by Wiley in Journal of the American Ceramic Society
- Vol. 81 (8) , 2205-2208
- https://doi.org/10.1111/j.1151-2916.1998.tb02610.x
Abstract
A complete range of perovskite solid solutions can be formed in the (1 −x)Ba(Mg1/3Nb2/3)O3‐xLa(Mg2/3Nb1/3)O3 (BMN‐LMN) pseudobinary system. While pure BMN adopts a 1:2 cation ordered structure, 1:1 ordered phases are stabilized for 0.05 ≤x≤ 1.0. Dark‐field TEM images indicate that the La‐doped solid solutions are comprised of large 1:1 ordered domains and no evidence was found for a phase‐separated structure. This observation coupled with the systematic variations in the intensities of the supercell reflections supports a charge‐balanced “random‐site” model for the 1:1 ordering. The substitution of La also induces a transformation from a negative to positive temperature coefficient of capacitance in the region 0.25 ≤x≤ 0.5.Keywords
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