An atom–dipole interaction model study of the molecular second hyperpolarizability of selected haloalkanes
- 15 February 1977
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 66 (4) , 1475-1476
- https://doi.org/10.1063/1.434109
Abstract
The group dipole interaction model of the molecular second hyperpolarizability is specialized to describe a molecule composed of interacting isotropic atoms. The model is applied to a set of selected haloalkanes, and using established values for the atom polarizabilities, the atom second hyperpolarizabilities for carbon, hydrogen, fluorine, chlorine, bromine, and iodine are evaluated. The experimental and theoretical molecular second hyperpolarizabilities agree to within an average of 15%.Keywords
This publication has 10 references indexed in Scilit:
- Second and third order hyperpolarizabilities of organic moleculesThe Journal of Chemical Physics, 1975
- Molecular second- and third-order polarizabilities from measurements of second-harmonic generation in gasesPhysical Review A, 1975
- Polarizability of the cyano group from a dipole interaction treatment of experimental polarizabilities of nitrilesThe Journal of Physical Chemistry, 1973
- Atom dipole interaction model for molecular polarizability. Application to polyatomic molecules and determination of atom polarizabilitiesJournal of the American Chemical Society, 1972
- Mesure des interactions entre ondes lumineuses dans diverses substancesJournal de Physique, 1971
- Kerr effect in methane and its four fluorinated derivativesTransactions of the Faraday Society, 1969
- Kerr effect in inert gases and sulphur hexafluorideTransactions of the Faraday Society, 1968
- Molecular hyperpolarisabilitiesQuarterly Reviews, Chemical Society, 1967
- The polarisabilities of bonds—ITransactions of the Faraday Society, 1940
- VII. Molecular refractivity and atomic interactionJournal of Computers in Education, 1917