Decomposition Kinetics, Arrhenius Parameters, and Bond Dissociation Energies for Alkoxyamines of Relevance in “Living” Free Radical Polymerization
- 25 November 1998
- journal article
- Published by American Chemical Society (ACS) in Macromolecules
- Vol. 31 (25) , 9103-9105
- https://doi.org/10.1021/ma9812229
Abstract
No abstract availableKeywords
This publication has 24 references indexed in Scilit:
- Radical reaction kinetics during homolysis of N-alkoxyamines: verification of the persistent radical effectJournal of the Chemical Society, Perkin Transactions 2, 1998
- The Role of Thermal Initiation in Nitroxide Mediated Living Free Radical PolymerizationsChemistry Letters, 1997
- Thermolysis of a Tertiary Alkoxyamine. Recombination and Disproportionation of α-Phenethyl/Diethyl Nitroxyl Radical PairsThe Journal of Organic Chemistry, 1997
- Influence of Acids on Reaction Rates of Free Radical Scavenging by TEMPO. Relevance to “Living” Free Radical PolymerizationsMacromolecules, 1996
- The Pivotal Role of Excess Nitroxide Radical in Living Free Radical Polymerizations with Narrow PolydispersityMacromolecules, 1996
- Alkoxyamine-Initiated Living Radical Polymerization: Factors Affecting Alkoxyamine Homolysis RatesMacromolecules, 1995
- Rate Enhancement of Living Free-Radical Polymerizations by an Organic Acid SaltMacromolecules, 1995
- Kinetics of decomposition of 2,2,6,6-tetramethyl-1-(1-phenylethoxy)piperidine and its implications on nitroxyl-mediated styrene polymerizationMacromolecules, 1995
- Free-Radical Polymerization for Narrow-Polydispersity Resins. Semiempirical Molecular Orbital Calculations as a Criterion for Selecting Stable Free-Radical Reversible TerminatorsMacromolecules, 1995
- Kinetics of nitroxide radical trapping. 2. Structural effectsJournal of the American Chemical Society, 1992