Highly Efficient β-Glucosylation of the Acidic Hydroxyl Groups, Phenol and Carboxylic Acid, with an Peracetylated Glucosyl Fluoride Using a Combination of BF3 · Et2O and DTBMP as a Promoter
- 1 October 1999
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1999 (10) , 1627-1629
- https://doi.org/10.1055/s-1999-12529
Abstract
A combination of BF3 · Et2O and DTBMP was established to be an efficient promoter of β-glucosylation of both phenols and carboxylic acids with a peracetylated glycosyl fluoride (2). This new method achieved remarkably high yields and β-selectivity.Keywords
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