Temperature dependence of an oxygen transfer reaction induced by the oxidation of a nitro complex of ruthenium(II), trans-[RuCl(NO2)(py)4](py = pyridine)
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1618-1620
- https://doi.org/10.1039/c39870001618
Abstract
A single electron oxidation of a nitro complex of RuII at 25 °C gives three complexes containing (RuIV O2–), (RuIII-OH–), and (RuII–NO+) moieties as final products, while two products involving (RuIII–ONO2 –) and (RuII–NO+) are formed at ca.–40 °C; at 25 °C the reaction appears to proceed from an intermediate species involving an (RuIII–O) moiety, generated during the oxidation process.Keywords
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