Asymptotic expansions for autocorrelation functions with Gaussian memory
- 1 December 1984
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 81 (11) , 5034-5042
- https://doi.org/10.1063/1.447490
Abstract
Mori’s integro-differential equation for equilibrium correlation functions is investigated for a Gaussian memory. For this type of memory the first four moments of the autocorrelation function are reproduced exactly. So far, however, the underlying Mori equation has only been solved numerically. In this paper analytic short-time and long-time expansions are derived by the aid of which the behavior of the autocorrelation function can be described in the whole time domain. The analysis shows that there exists a critical parameter τc which separates the regime of oscillatory from that of nonoscillatory decay of the autocorrelation function. Finally, the Gaussian memory results are compared with those of an exponential memory.Keywords
This publication has 13 references indexed in Scilit:
- Low temperature heat conductivity of the cooperative vibronic system TmVO4Solid State Communications, 1984
- The molecular dynamics simulations of the damping matrices in a Lennard-Jones fluid and testing of the two-relaxation time models for the memory functionThe Journal of Chemical Physics, 1982
- Dynamics of quasi-one- and two-dimensional spin systems in the high-temperature limitJournal of Physics C: Solid State Physics, 1982
- Perturbation theory for orientational time-correlation functionsMolecular Physics, 1981
- Some exact results for rotational correlation functions at short timesMolecular Physics, 1981
- On the equivalence of generalized Langevin equation and generalized master equationZeitschrift für Physik B Condensed Matter, 1977
- Space-Time Correlations in Exchange-Coupled Paramagnets at Elevated TemperaturesPhysical Review B, 1969
- On the Velocity Autocorrelation in a Classical FluidPhysical Review B, 1967
- A Continued-Fraction Representation of the Time-Correlation FunctionsProgress of Theoretical Physics, 1965
- Transport, Collective Motion, and Brownian MotionProgress of Theoretical Physics, 1965