CONFIGURATIONAL PRODUCT CONTROL IN REACTIONS OF TRANS- AND CIS-DIALKYLBIS(TERTIARY PHOSPHINE)PALLADIUM(II) WITH CARBON MONOXIDE. EVIDENCE SUPPORTING AN ALKYL MIGRATION MECHANISM IN CO INSERTION INTO Pd–C BOND
- 5 March 1981
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 10 (3) , 289-292
- https://doi.org/10.1246/cl.1981.289
Abstract
Reactions of trans- and cis-PdR2L2 (R = Me, Et, Pr, and Bu; L = tertiary phosphine ligands) with carbon monoxide in solutions were found to give strikingly different products depending on the configurations of the dialkylpalladium complexes. The results can be explained reasonably by assuming reactions proceeding by alkyl migration mechanisms.This publication has 8 references indexed in Scilit:
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