Kinetic Studies on Solvolysis. VIII. Phenolysis of Optically Active α-Phenethyl Chloride in Phenol-Benzene Solven—Three-stage Mechanism in the SN1-Type Solvolysis
- 1 April 1962
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 35 (4) , 525-531
- https://doi.org/10.1246/bcsj.35.525
Abstract
1. Titrimetric and polarimetric rate constants (Kt and kα) for phenolysis of α-phenethyl chloride in 50wt.% phenol-benzene at 25°C were measured, and satisfactory first-order behavior was observed irrespective of presence or absence of anilinium phenolate. From this the SN1-characteristics of this phenolysis was concluded.Keywords
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