Fabrication of Novel Electrochemical Reduction Systems Using Alcohol Dehydrogenase as a Bifunctional Electrocatalyst
- 1 February 1996
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 25 (2) , 137-138
- https://doi.org/10.1246/cl.1996.137
Abstract
Electrochemical reduction of NADP+ to NADPH and of NAD+ to NADH with current efficiencies of more than 97% has been achieved at alcohol dehydrogenase (ALDH) in the presence of acetophenone as an electron mediator. Addition of acetone or acetaldehyde as a substrate to the above electrolytic system allowed reduction of the substrate to the corresponding alcohol at ALDH accompanied by oxidation of the resulting NAD(P)H.Keywords
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