Unsymmetrically-substituted [2,2]metacyclophanes via a free-radical substitution reaction
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 220-221
- https://doi.org/10.1039/c39730000220
Abstract
Substitution of [2,2]metacyclophane (1) with out transannular bonding has been performed using BzO·OBz–CuCl2–MeCN, to produce the 4-benzoate (3a) and the 8-cyanomethyl derivative (4).Keywords
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