Broad-band dielectric spectroscopy on morpholine/n-butanol liquid mixtures
- 1 July 1991
- journal article
- Published by IOP Publishing in Journal of Physics: Condensed Matter
- Vol. 3 (26) , 5073-5077
- https://doi.org/10.1088/0953-8984/3/26/023
Abstract
At 30 degrees C the complex (dielectric) permittivity of the system morpholine/n-butanol has been measured as a function of frequency nu (5*104 Hz10 Hz) and mole fraction x (0<or=x<or=1). Within the frequency range under consideration all liquids show a relaxation region with an underlying unsymmetrical distribution of relaxation times. The static permittivity, the characteristic dielectric relaxation time, and the width of the relaxation time distribution function are discussed. Other than what is expected on the grounds of recent permittivity measurements at 100 kHz no unusual properties are found for the binary mixtures.Keywords
This publication has 12 references indexed in Scilit:
- Broad-band dielectric spectroscopy on carboxylic acid/water mixtures. Dependence upon compositionThe Journal of Physical Chemistry, 1991
- Excess compressibility and excess dielectric constant for a morpholine-n-butyl alcohol liquid mixtureJournal of Physics: Condensed Matter, 1990
- Hydrogen bonding in liquid methanolThe Journal of Chemical Physics, 1990
- Dielectric spectra of some common solvents in the microwave region. Water and lower alcoholsChemical Physics Letters, 1990
- Diffusion effects of hydrogen bond fluctuations. I. The long time regime of the translational and rotational diffusion of waterThe Journal of Chemical Physics, 1989
- The Complex Dielectric Spectrum of Aqueous Methanol and Isopropanol SolutionsZeitschrift für Physikalische Chemie, 1989
- Large local energy fluctuations in waterThe Journal of Chemical Physics, 1987
- Dielectric spectroscopy on some aqueous solutions of 3:2 valent electrolytes. A combined frequency and time domain study.Journal of Molecular Liquids, 1987
- Dielectric Relaxation Study of Aqueous Methanol--Butanol Solutions. A Comparison with Higher Homologues.Acta Chemica Scandinavica, 1984
- Dielectric Relaxation Studies of Aqueous Long-chain Alcohol Solutions.Acta Chemica Scandinavica, 1984