Stereoselective Allyl AmineSynthesis via Enantioselective Addition ofDiethylzincand Sigmatropic Rearrangement; Synthesis of Lentiginosine
- 20 May 2003
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 2003 (7) , 1034-1036
- https://doi.org/10.1055/s-2003-39314
Abstract
A new synthetic method for the preparation of allyl amine derivatives has been developed. The key steps of this method are enantioselective addition of diethylzinc (Soai protocol) and allyl cyanate-to-isocyanate rearrangement. Successful application of this procedure realized the synthesis of lentiginosine (6).Keywords
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