Thermodynamics: A Riemannian geometric model
- 1 October 1979
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 20 (4) , 1608-1613
- https://doi.org/10.1103/physreva.20.1608
Abstract
By including the theory of fluctuations in the axioms of thermodynamics it is shown that thermodynamic systems can be represented by Riemannian manifolds. Of special interest is the curvature of these manifolds which, for pure fluids, is associated with effective interparticle interaction strength by means of a general thermodynamic "interaction hypothesis." This interpretation of curvature appears to be consistent with hyperscaling and two-scale-factor universality. The Riemannian geometric model is a new attempt to extract information from the axioms of thermodynamics.Keywords
This publication has 14 references indexed in Scilit:
- Functional integration and the Onsager-Machlup Lagrangian for continuous Markov processes in Riemannian geometriesPhysical Review A, 1979
- Two-scale-factor universality near the critical point of fluidsPhysics Letters A, 1978
- Thermodynamics and geometryPhysics Today, 1976
- Scaled equation of state parameters for gases in the critical regionJournal of Physical and Chemical Reference Data, 1976
- Metric geometry of equilibrium thermodynamicsThe Journal of Chemical Physics, 1975
- The critical point and scaling theoryPhysica, 1974
- Universality of Second-Order Phase Transitions: The Scale Factor for the Correlation LengthPhysical Review Letters, 1972
- Critical Points in Multicomponent SystemsPhysical Review A, 1970
- Surface Tension and Molecular Correlations near the Critical PointThe Journal of Chemical Physics, 1965
- GENERALIZED THERMODYNAMICS INCLUDING THE THEORY OF FLUCTUATIONSJournal of the American Chemical Society, 1931