Addition of nucleophilic metal complexes to mononuclear transition metal carbyne compounds; X-ray crystal structure of [PtW(µ-CC6H4-p-Me)(CO)2(PMe2Ph)2(η-C5H5)]
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 42-43
- https://doi.org/10.1039/c39790000042
Abstract
Compounds containing platinum–tungsten bonds with bridging carbyne ligands are formed by reaction of the species [Pt(C2H4)(PR3)2](PR3= PMe3 or PMe2Ph) with carbyne complexes [W(CR)(CO)2(η-C5H5)] or [WBr(CR)(CO)4](R = C6H4-p-Me); X-ray diffraction studies have established the structure of [PtW(µ-CC6H4-p-Me)(CO)2(PMe2Ph)2(η-C5H5)].Keywords
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