Polymer-Supported Ammonium Fluoride: A Useful Reagent for Si-O Bond Cleavage
- 1 June 1991
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 21 (12-13) , 1315-1320
- https://doi.org/10.1080/00397919108021278
Abstract
Polymer-supported ammonium fluoride (1) is a convenient reagent for Si-O bond cleavage. Resin 1 is inexpensive, easy to prepare from commercial amine-containing anion exchange resins and aqueous hydrofluoric acid, easy to store. The product is easily separated from the reaction mixture by filtration. The used resins can be regenerated and reused without losing its reactivity.Keywords
This publication has 4 references indexed in Scilit:
- Methylammonium Fluoride (MAF): A Convenient Reagent for Si-O Bond CleavageSynthetic Communications, 1989
- Use of Organosilicon Reagents as Protective Groups in Organic SynthesisSynthesis, 1985
- Hydrogen bond assisted reactions: C- and O-alkylations, sulphenylations, and Michael additions aided by polymer immobilized fluoride ionCanadian Journal of Chemistry, 1979
- Total synthesis of (+-)-fumagillinJournal of the American Chemical Society, 1972