Ruthenium-cluster-catalysed reductive carbonylation of nitrobenzene: X-ray structure of [Ph4P][Ru3(CO)10(PhNCHO)], a catalytic intermediate
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 515-516
- https://doi.org/10.1039/c39890000515
Abstract
The ruthenium cluster [Ph4P][Ru3(CO)10(PhNCHO)] has been structurally characterised and shown to play an important role, along with its precursor [Ph4P][HRu3(CO)9(PhNCO)], in the hydroxide- or methoxide-promoted reductive carbonylation of nitrobenzene.Keywords
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