A simple procedure for the elaboration of carbonyl compounds into homologous alkynes
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 8,p. 869-874
- https://doi.org/10.1039/p19770000869
Abstract
The base-induced reaction of diazomethyltrimethylsilane (1) or of the dialkyl diazomethylphosphonates (4) and (5) with aromatic carbonyl compounds leads directly to the corresponding homologous alkynes. The mechanism, scope, and limitations of this synthetically useful process have been investigated.Keywords
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