Spectroscopic identification of the haem ligands of cellobiose oxidase

Abstract
A spectroscopic study of the flavocytochrome b enzyme, cellobiose oxidase, employing optical, NMR, EPR and near infra‐red MCD techniques, has identified the axial ligands of the b‐type haem. These are a histidine and a methionine, and this ligation set is discussed in relation to the functional role of the haem group.

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