Some reactions of O,O-diphenylphosphoryl azide
Open Access
- 1 January 1973
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 26 (7) , 1591-1593
- https://doi.org/10.1071/ch9731591
Abstract
Diphenylphosphoryl azide, in contrast to N,N?-disubstituted phosphorodiamidic azides, undergoes nucleophilic displacement of the azido group by reaction with water, butanol, ammonia, and amines. Possible mechanisms for the conversion of diphenyl-phosphoryl azide into urethanes and amides are briefly discussed. Pyrolysis of N,N?- dicyclohexylphosphorodiamidic azide gave the phosphenimidic amide dimer.Keywords
This publication has 0 references indexed in Scilit: