Ligand and induced internal electron transfer pathways to new Mo–S and W–S dithiocarbamate complexes
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 927-929
- https://doi.org/10.1039/c39850000927
Abstract
Addition of tetra-alkylthiuram disulphides [R2NC(S)S–SC(S)NR2] to MOVIS4 2–, WVIS4 2– and MOVIO2S2 2–yields the new complexes MoV(S2)(S2CNR2)3 and WVIS(S2)(S2CNR2)2 and the known complex MoVIO(S2)(S2CNR2)2, respectively, revealing redox behaviour involving induced internal electron transfer and lignad electron transfer processes.Keywords
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