Hydrocarbon–metal nitrosyls. Part II. Acyl derivatives of tricarbonylnitrosyliron, and their reactions with dienes

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Abstract
Sodium tricarbonylnitrosylferrate reacts with alkyl halides to give tricarbonylnitrosylacylirons. These react with dienes to yield allyl complexes substituted by acyl groups on the terminal carbon atom of the diene used. Reaction with triphenylphosphine led to displacement of one molecule of carbon monoxide from these products; with the allyl complexes there was also some replacement of nitric oxide and hydrogen with formation of acyldienedicarbonyl(triphenylphosphine)irons.

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