HFClF: Structure and bonding

Publisher Website
Google Scholar
Abstract
The structure of the complex formed between HF and ClF has been determined by molecular beam electric resonance spectroscopy. The molecule HFClF is a slightly asymmetric prolate top. The spectroscopic constants determined from K=0 spectra of several isotopic species are as follows: The atomic arrangement in the complex is HFClF with the three heavy atoms collinear. The proton is off axis by 55°. The FCl van der Waals bond length is 2.76 Å. Comparison of the structure of HFClF with that of (HF)2 shows striking similarities. It appears that the bonding in both complexes is quite similar.

This publication has 9 references indexed in Scilit: