SYNTHESIS AND CONFORMATION OF 1,2,4-TRI-O-ACTYL-5,6-DIDOXY-3-O-METHYL-5-C-[(S)-PHENYLPHOSPHINYL]-β-d-GLUCOPYRANOSE
- 5 August 1978
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 7 (8) , 871-872
- https://doi.org/10.1246/cl.1978.871
Abstract
Hydrolysis of phenylphosphinyl derivative of hexofuranose (1) followed by acetylation gave two compounds. The X-ray analysis of one component revealed the structure to be 1,2,4-tri-O-acetyl-5,6-dideoxy-3-O-methyl-5-C-[(S)-phenylphosphinyl]-β-d-glucopyranose (3a) which had a 4C1 (d) conformation.This publication has 2 references indexed in Scilit:
- A novel method for the synthesis of sugar derivatives containing a phosphorus atom in the hemiacetal ringCarbohydrate Research, 1977
- X-ray analysis of 1-phenyl-4-phosphorinanone. Evidence for a chair conformation with an axial substituentJournal of the American Chemical Society, 1971