The synthesis, structural and spectroscopic studies of [Ru2Rh2H2(CO)12]
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 3,p. 681-686
- https://doi.org/10.1039/dt9860000681
Abstract
The synthesis of [Ru2Rh2H2(CO)12] is reported, together with X-ray structural and multinuclear, variable-temperature n.m.r. studies. The structure, both in the solid state and at low temperature in solution, is related to that of [Rh4(CO)12] with one basal rhodium and the apical rhodium atoms being replaced by ruthenium atoms; the hydrogen atoms are both bonded to the apical ruthenium and bridge Ru–Ru and Ru–Rh edges of the Ru2Rh2 tetrahedron. At higher temperatures, both hydrogen and carbonyl fluxionality is observed.Keywords
This publication has 0 references indexed in Scilit: