Nuclear magnetic resonance studies on metal complexes. Part VI. Complexes of the type [IrX₃(CO)L₂](L = Cl, Br, or l; L = PMe₂Ph or AsMe₂Ph), including a study of iridium–chlorine stretching frequencies

1 January 1968

journal article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 2784-2787
https://doi.org/10.1039/j19680002784

Abstract

Proton (methyl) magnetic resonance spectral data are given for a series of iridium(III) complexes of type [IrX₃(CO)L₂], (X = Cl, Br, or I; L = PMe₂Ph or AsMe₂Ph. The preparation of the complexes and the interconversion of the different configurations are described. Values of ν(Ir–Cl) depend mainly on the trans-ligand and decrease in the order Cl > CO > PMe₂Ph AsMe₂Ph.

Keywords

NUCLEAR MAGNETIC RESONANCE

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Nuclear magnetic resonance studies on metal complexes. Part VI. Complexes of the type [IrX3(CO)L2](L = Cl, Br, or l; L = PMe2Ph or AsMe2Ph), including a study of iridium–chlorine stretching frequencies

Abstract

Keywords

Nuclear magnetic resonance studies on metal complexes. Part VI. Complexes of the type [IrX₃(CO)L₂](L = Cl, Br, or l; L = PMe₂Ph or AsMe₂Ph), including a study of iridium–chlorine stretching frequencies